Question 1
[20]
1.1 Calculate the lattice constant of Iron. Given density of iron 7.86 kg/cm?, atomic
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weight of iron 55.85 and Avogadro’s number 6.023 x 107°/kmol.
1.2 Sketch the unit cell and show the following planes (112), (101), (123)
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2.3. Show that the atomic packing factor for FCC and HCP metals are the same.
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Question 2
[20]
2.1 What is Madelung constant? What is its significance?
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2.2
How are secondary bonds formed? Give names of secondary bonds.
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2.3
Compute the net potential energy of a simple Na*CI pair. The equilibrium distance between the
ions is 0.28nm. The potential energy due to repulsion between electron sis given by Ur=B/r® — (10)
Question 3
[20]
3.1 | What is meant by phonons? Do phonons have mass?
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3.2. What is lattice wave? Calculate the value of cutoff frequency in a solid assuming a linear lattice. (6)
If velocity of sound in a solid is 3 x 10° m/s and Interatomic distance is 5 x 107° m.
3.3
What is Einstein theory of specific heat? Derive an expression for heat capacity of a
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solid based on Einstein theory.
Question 4
[20]
4.1
Give the assumptions of the classical free electron theory.
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4.2
State and explain Wiedemann-Franz law? Calculate Lorentz number, given the thermal and
electrical conductivities of Cu at 20°C are 390 WmK* and 5.87 x10’Q:'m? respectively
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4.3
Using the free electron mode, derive an expression for electrical conductivity in metals.
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