QUESTION 1
[30]
1.1 Briefly explain the following thermodynamic terms:
(10)
(a) Surrounding
(b) Open system
(c) Heat
(d) Thermal equilibrium
(e) An isolated system
1.2 Ona brisk autumn day (3.0°C) the tires of a car were inflated to a pressure of
2.80 x 10° Pa. The tire gauge reads 1.4 x 10° Pa, but this is the excess above
atmospheric pressure, which is about 1.01 x 105 Pa. Assuming that the tires and
air inside are in equilibrium with the outside air, what is the Kelvin temperature of
the air inside?
(2)
1.3 A copper strip is 50.0 mm long at 0°C. How long would it be at 150°C if the coefficient
of linear expansion for Brass is 1.7 x 10° °C +?
(3)
1.4 (a) Estimate the amount of heat needed to raise the temperature of 50.0 g of lead
(c = 1.28x107 J.kg+ K+) from 2.3 °C to 196.0 °C.
(3)
(b) At 16.0°C, a brass cube has an edge length of 30.0 cm. What is the increase in
the cube’s volume when it is heated to 81.0°C? The coefficient of linear expansion
for brass is given by a = 19.00 x 10° °C?.
(5)
1.5 A2.00 g sample of methanol (cm = 2450 J.kg+ K+) at 20°C is mixed with 1.00 g of water
(cw = 4180 J.kg* K*) at 60°C. The system is insulated and attains its equilibrium
temperature Teg.
a) Using the definition of specific heat, set up the Qtotal = 0 equation.
(3)
b) Calculate the final temperature 7; of the mixture.
(4)
QUESTION 2
[24]
2.1 State the 2" Law of thermodynamics and write its differential form.
(5)
2.2 What is isochoric (isometric) process? If 1265 J of heat energy is expelled from a gas
confined in an isochoric process, evaluate the change in internal energy of the gas.
(4)
2.2 State the molar specific heats of an ideal gas and discuss how these molar specific
heats are related. Also, write down the ratio y in terms of these specific heats.
(4)
2.4 An ideal gas undergoes an isothermal expansion at temperature T, changing its
volume from V; to V;. Use an ideal gas law to show that the work done during an
Page 2 of 3