Question 1
[20]
1.1
Distinguish the Lattice energy and cohesive energy.
(4)
1.2
In a crystal whose primitives are 0.12nm, 0.18nm and 0.2 nm, a plane (231)’ has an intercept
(6)
of 0.12 nm on the x-axis. Find the intercept on the y and z axes.
1.3
(a) Calculate the next neighbour’s distance in a body centred cubic crystal
(5)
(b) In a body centred cubic lattice, find the ratio of the nearest neighbour’s
(5)
distance to the next neighbour’s distance.
Question 2
[20]
2A.
How are dispersion bonds formed in a molecular solid?
(4)
2.2
How do you identify lonics, covalent and metallic bonds in solids
(6)
2.3
Draw and explain energy vs interatomic distance curve. Compare it with force vs interatomic —_ (10)
distance graphs
Question 3
[20]
3.1
What causes phonons in lattice vibration? Which crystals exhibit optical phonon modes?
(4)
3.2
If the velocity of sound in a solid is of the order 10° m/s, compare the frequency of the sound
(6)
wave with A = 20 A for (i) a monoatomic system and (ii) acoustic waves and optical waves ina
diatomic system containing two identical atoms (M=m) per unit cell of interatomic spacing 2.2 A.
3.3
What is lattice specific heat? Drive heat capacity of solid crystalline substances at room
(10)
temperature is 3 R.
Question 4
[20]
4.1 Explain the terms: a) Drift velocity b) Relaxation time c) Mean free path
(4)
d) Mean collision time for free electrons.
4.2
The density and atomic weight of Cu are 8900 kg.m® and 63.5. The relaxation time of electrons (6)
in Cu at 300K is 107s. Calculate the electrical conductivity of copper.
4.3
Derive Ohm’s law based on Drude’s Free Electron Theory?
(10)